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Luperox® TBH70X, tert-Butyl hydroperoxide solution

458139 -

70 wt. % in H2O

DOWNLOAD MSDS (PDF)

Synonym: 1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane, tert-Butyl hydroperoxide solution, TBHP

  • CAS Number: 75-91-2

  • Linear Formula: (CH3)3COOH

  • Molecular Weight: 90.12

  • Beilstein Registry Number: 1098280

  • MDL number: MFCD00002130

  • PubChem Substance ID: 24869433

Properties

Related CategoriesFree Radical Initiators, Organic Peroxides, Oxidation, Peroxides, Polymerization Initiators,
concentration70 wt. % in H2O
refractive indexn20/D 1.386
bp96.2 °C
density0.93 g/mL at 25 °C

Description

Packaging

1, 4 L in poly btl

18 L in poly drum

25, 100 mL in poly btl

Legal Information

Product of Arkema Inc.

Luperox is a registered trademark of Arkema Inc.

Application

Versatile reagent for oxidations.1,2,3,4

Price and Availability

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Documents

Certificate of Analysis

Certificate of Origin

FT-IR Raman
FT-NMR
Structure Search
Pressure-Temperature Nomograph
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Safety Information

SymbolGHS02GHS05GHS06GHS08GHS09  GHS02, GHS05, GHS06, GHS08, GHS09
Signal wordDanger
Hazard statementsH226-H242-H302-H311-H314-H317-H331-H341-H411
Precautionary statementsP220-P261-P273-P280-P305 + P351 + P338-P310
Personal Protective EquipmentFaceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard CodesO,C
Risk Statements7-10-20/21/22-34-52/53
Safety Statements14-26-3/7-36/37/39-45-61
RIDADRUN 3109 5.2
WGK Germany3
Flash Point(F)107.6 °F
Flash Point(C)42 °C
Technical information & documentation associated with this product is available in the Safety & Documentation tab.

Articles

CBHA Ligands

Yamamoto and his group developed a new type of ligands based on the C2-symmetric chiral bishydroxamic acid (CBHA). These bidentate ligands have pendant "arms" that can be substituted with a variety o...
Dr. Daniel Weibel
Chemfiles Volume 10 Article 1
Keywords: Asymmetric synthesis, Building blocks, Catalog, Epoxidations, Jacobsen Epoxidation, Ligands, Oxidations, Sharpless Epoxidation

References

1. Inorg. Chim. Acta 357, 2237-2244, (2004)

2. J. Catal. 224, 288-296, (2004)

3. Sci. Synth. 3, 91-131, (2004)

4. J. Chem. Res. Synop. 7, 390-394, (2003)

Aldrichimica Acta 12, 63, (1979)

Merck 14,1570

Beil. 1,IV,1616

Structure Index 1, 16:A:6


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